| Marcel Granollers (1) | | | | Horacio Zeballos (1) | 6 | 6 | | John Patrick Smith (Ersatz) | 4 | 4 | | Miguel Reyes Varela (Ersatz) | | |
| | Marcel Granollers (1) | | Horacio Zeballos (1) | | |
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| Jamie Murray (WC) | | John Peers (WC) | | Adrian Mannarino | Ugo Humbert |
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| Alejandro Tabilo | | | | | Luciano Darderi | 7 | 4 | 11 | | Stefanos Tsitsipas (Ersatz) | 5 | 6 | 9 | Petros Tsitsipas (Ersatz) | | | |
| | Alejandro Tabilo | | Luciano Darderi | | |
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| Jean-Julien Rojer | | Adam Pavlásek | | Harri Heliövaara (6) | | Henry Patten (6) |
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| Simone Bolelli (4) | Andrea Vavassori (4) | | Zhizhen Zhang | | Tomáš Macháč |
| | | | Aoran Wang (WC) | Yi Zhou (WC) |
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| Fabien Reboul | | | Sadio Doumbia | 6 | 4 | | Aoran Wang (WC) | 73 | 6 | Yi Zhou (WC) | | |
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| Máximo González | | | | Andrés Molteni | 74 | 4 | 10 | | Hugo Nys | 6 | 6 | 6 | | Jan Zieliński | | | |
| | Máximo González | Andrés Molteni | | Karen Khachanov | Andrey Rublev |
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| Karen Khachanov | | | Andrey Rublev | 7 | 7 | | Michael Venus (7) | 5 | 5 | | Neal Skupski (7) | | |
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| Rajeev Ram (8) | | | | Austin Krajicek (8) | 4 | 6 | 14 | | Marcelo Melo | 6 | 3 | 12 | Rafael Matos | | | |
| | Rajeev Ram (8) | Austin Krajicek (8) | | Édouard Roger-Vasselin | | Santiago González |
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| Édouard Roger-Vasselin | | | | Santiago González | 6 | 6 | | Frances Tiafoe | 2 | 2 | | Alexander Bublik | | |
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| Ariel Behar | | | | Robert Galloway | 6 | 6 | | Rigele Te (WC) | 3 | 4 | Fajing Sun (WC) | | |
| | Ariel Behar | | Robert Galloway | | Lloyd Glasspool | Julian Cash |
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| Lloyd Glasspool | | | Julian Cash | 76 | 73 | | Matthew Ebden | 6 | 6 | | Joe Salisbury | | |
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| Rohan Bopanna (5) | | | | Ivan Dodig (5) | 6 | 6 | | Pablo Carreño Busta | 4 | 3 | Pedro Martínez | | |
| | Rohan Bopanna (5) | | Ivan Dodig (5) | | Nikola Mektić | | Wesley Koolhof |
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| Nikola Mektić | | | | | Wesley Koolhof | 6 | 3 | 10 | | Arthur Fils | 3 | 6 | 4 | | Ben Shelton | | | |
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| Jackson Withrow | | | Nathaniel Lammons | 6 | 6 | | Tomás Martín Etcheverry | 3 | 3 | Francisco Cerúndolo | | |
| | Jackson Withrow | Nathaniel Lammons | | Sander Gillé | Joran Vliegen |
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| Sander Gillé | | | | Joran Vliegen | 2 | 6 | 10 | | Mate Pavić (2) | 6 | 3 | 5 | | Marcelo Arévalo (2) | | | |
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