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| Rafael Nadal (1) | 76 | 6 | | Daniel Evans (Q) | 6 | 4 |
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| Rafael Nadal (1) | 6 | 6 | | Guido Pella | 3 | 4 |
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| Rafael Nadal (1) | 2 | 6 | 6 | | Fabio Fognini (7) | 6 | 1 | 2 |
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| Rafael Nadal (1) | w.o. | | Gaël Monfils (16) | |
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| Rafael Nadal (1) | 6 | 6 | | Daniil Medvedev (8) | 3 | 0 |
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| Alex de Minaur | 4 | 6 | | Daniel Evans (Q) | 6 | 76 |
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| Radu Albot | 6 | 6 | | Gilles Simon | 4 | 2 |
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| Radu Albot | 3 | 6 | 6 | | Guido Pella | 6 | 2 | 72 |
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| Guido Pella | 6 | 74 | | David Goffin (15) | 4 | 6 |
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| Borna Ćorić (11) | 2 | 6 | 72 | | Peter Gojowczyk | 6 | 1 | 6 |
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| Borna Ćorić (11) | 2 | 1 | | Adrian Mannarino | 6 | 6 |
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| Adrian Mannarino | 2 | 5 | | Fabio Fognini (7) | 6 | 7 |
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| Mikhail Kukushkin | 4 | 4 | | Adrian Mannarino | 6 | 6 |
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| Tommy Paul (Q) | 6 | 6 | | Brayden Schnur (WC) | 1 | 2 |
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| Tommy Paul (Q) | 6 | 3 | | Fabio Fognini (7) | 73 | 6 |
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| Stefanos Tsitsipas (4) | | (BYE) |
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| Stefanos Tsitsipas (4) | 4 | 6 | 3 | | Hubert Hurkacz (Ersatz) | 6 | 3 | 6 |
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| Hubert Hurkacz (Ersatz) | 4 | 0 | | Gaël Monfils (16) | 6 | 6 |
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| Gaël Monfils (16) | 6 | 3 | 72 | | Roberto Bautista-Agut (10) | 4 | 6 | 6 |
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| Hubert Hurkacz (Ersatz) | 6 | 7 | | Taylor Fritz | 3 | 5 |
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| Ilya Ivashka (Q) | 73 | 6 | | Soonwoo Kwon (Q) | 6 | 4 |
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| Ilya Ivashka (Q) | 3 | 6 | | Gaël Monfils (16) | 6 | 76 |
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| Peter Polansky (WC) | 74 | 3 | 3 | | Gaël Monfils (16) | 6 | 6 | 6 |
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| Roberto Bautista-Agut (10) | 6 | 6 | | Bernard Tomic (Q) | 3 | 2 |
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| Roberto Bautista-Agut (10) | 6 | 7 | | Diego Schwartzman | 2 | 5 |
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| Roberto Bautista-Agut (10) | 7 | 7 | | Richard Gasquet | 5 | 5 |
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| Marco Cecchinato | 6 | 6 | 4 | | Diego Schwartzman | 3 | 75 | 6 |
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| Benoît Paire | 6 | 4 | | Richard Gasquet | 72 | 6 |
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| Richard Gasquet | 6 | 6 | 74 | | Kei Nishikori (5) | 76 | 2 | 6 |
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| Karen Khachanov (6) | 6 | 6 | 6 | | Stan Wawrinka | 4 | 73 | 2 |
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| Karen Khachanov (6) | 6 | 7 | 6 | | Félix Auger-Aliassime | 77 | 5 | 3 |
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| Karen Khachanov (6) | 6 | 6 | | Alexander Zverev (3) | 3 | 3 |
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| Karen Khachanov (6) | 1 | 6 | | Daniil Medvedev (8) | 6 | 76 |
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| Stan Wawrinka | 6 | 6 | | Grigor Dimitrov | 4 | 4 |
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| Félix Auger-Aliassime | 6 | 6 | 73 | | Vasek Pospisil (WC) | 2 | 73 | 6 |
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| Félix Auger-Aliassime | 6 | 3 | | | Milos Raonic (17) | 3 | 6 | Aufg. |
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| Lucas Pouille | 4 | 4 | | Milos Raonic (17) | 6 | 6 |
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| Nikoloz Basilashvili (13) | 3 | 6 | 6 | | Dušan Lajović | 6 | 4 | 4 |
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| Nikoloz Basilashvili (13) | 2 | 6 | 6 | | Jan-Lennard Struff | 6 | 2 | 3 |
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| Nikoloz Basilashvili (13) | 5 | 7 | 6 | | Alexander Zverev (3) | 7 | 5 | 75 |
|
| Jan-Lennard Struff | 6 | 6 | | Jo-Wilfried Tsonga (WC) | 2 | 2 |
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| Márton Fucsovics | 7 | 2 | 3 | | Cameron Norrie | 5 | 6 | 6 |
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| Cameron Norrie | 6 | 4 | | Alexander Zverev (3) | 74 | 6 |
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| (BYE) | | Alexander Zverev (3) |
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|
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| Daniil Medvedev (8) | 6 | 6 | | Kyle Edmund | 3 | 0 |
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| Daniil Medvedev (8) | 6 | 6 | | Cristian Garín | 3 | 3 |
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| Daniil Medvedev (8) | 6 | 6 | | Dominic Thiem (2) | 3 | 1 |
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| Nick Kyrgios | 3 | 4 | | Kyle Edmund | 6 | 6 |
|
| Laslo Djere | 2 | 6 | | Cristian Garín | 6 | 74 |
|
| Cristian Garín | 6 | 6 | | John Isner (12) | 3 | 4 |
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| Jordan Thompson | 6 | 3 | 6 | | John Isner (12) | 3 | 6 | 76 |
|
| Marin Čilić (14) | 6 | 77 | | Bradley Klahn (Q) | 3 | 6 |
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| Marin Čilić (14) | 6 | 6 | | John Millman (LL) | 3 | 4 |
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| Marin Čilić (14) | 6 | 4 | | Dominic Thiem (2) | 77 | 6 |
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| John Millman (LL) | 6 | 72 | 6 | | Feliciano López (Q) | 74 | 6 | 3 |
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| Pierre-Hugues Herbert | 3 | 5 | | Denis Shapovalov | 6 | 7 |
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| Denis Shapovalov | 4 | 6 | 3 | | Dominic Thiem (2) | 6 | 3 | 6 |
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