| | Carlos Alcaraz (1) | 6 | 6 | | Facundo Bagnis | 0 | 2 |
| | Carlos Alcaraz (1) | 6 | 75 | | Dušan Lajović | 0 | 6 |
| | Carlos Alcaraz (1) | 6 | 6 | | Tommy Paul (16) | 4 | 4 |
| | Carlos Alcaraz (1) | 6 | 6 | | Taylor Fritz (9) | 4 | 2 |
| | Carlos Alcaraz (1) | | Jannik Sinner (10) |
| |
| Felipe Meligeni Alves (Q) | 3 | 6 | 4 | | Facundo Bagnis | 6 | 1 | 6 |
|
| Andy Murray | 4 | 5 | | Dušan Lajović | 6 | 7 |
| | Dušan Lajović | 6 | 72 | | Maxime Cressy (30) | 4 | 6 |
|
|
| Alejandro Davidovich Fokina (20) | | (BYE) |
| | Alejandro Davidovich Fokina (20) | 6 | 75 | | Brandon Nakashima | 4 | 6 |
| | Alejandro Davidovich Fokina (20) | 3 | 5 | | Tommy Paul (16) | 6 | 7 |
|
| Oscar Otte | 6 | 3 | | Brandon Nakashima | 73 | 6 |
|
| Marc-Andrea Hüsler | 6 | 72 | 6 | | Albert Ramos Viñolas | 74 | 6 | 3 |
| | Marc-Andrea Hüsler | 7 | 3 | 4 | | Tommy Paul (16) | 5 | 6 | 6 |
|
|
| | Taylor Fritz (9) | 6 | 6 | | Emilio Nava (WC) | 4 | 1 |
| | Taylor Fritz (9) | 6 | 6 | | Denis Shapovalov (24) | 4 | 4 |
| | Taylor Fritz (9) | 6 | 6 | | Holger Rune (7) | 3 | 4 |
|
| Emilio Nava (WC) | 75 | 74 | | John Isner | 6 | 6 |
|
| Guido Pella | 1 | 6 | 6 | | Juan Pablo Varillas | 6 | 3 | 2 |
| | Guido Pella | 3 | 6 | 3 | | Denis Shapovalov (24) | 6 | 3 | 6 |
|
| (BYE) | | Denis Shapovalov (24) |
|
| Diego Schwartzman (31) | | (BYE) |
| | Diego Schwartzman (31) | 71 | 6 | | Yibing Wu | 6 | 1 |
| | Diego Schwartzman (31) | 4 | 2 | | Holger Rune (7) | 6 | 6 |
|
|
| Pedro Cachín | 4 | 6 | | Márton Fucsovics | 6 | 72 |
| | Márton Fucsovics | 3 | 5 | | Holger Rune (7) | 6 | 7 |
|
|
| | Casper Ruud (3) | 6 | 6 | | Ilya Ivashka | 2 | 3 |
| | Casper Ruud (3) | 6 | 4 | 4 | | Botic van de Zandschulp (26) | 3 | 6 | 6 |
| | Botic van de Zandschulp (26) | 6 | 4 | 5 | | Emil Ruusuvuori | 4 | 6 | 7 |
| | Emil Ruusuvuori | 3 | 1 | | Jannik Sinner (10) | 6 | 6 |
|
| Ilya Ivashka | 6 | 6 | | Daniel Altmaier (Q) | 2 | 1 |
|
| Alexei Popyrin | 75 | 4 | | | Mikael Ymer | 6 | 4 | Ret. |
| | Alexei Popyrin | 6 | 6 | 2 | | Botic van de Zandschulp (26) | 4 | 74 | 6 |
|
| (BYE) | | Botic van de Zandschulp (26) |
|
| Roberto Bautista Agut (22) | | (BYE) |
| | Roberto Bautista Agut (22) | 4 | 6 | | Emil Ruusuvuori | 6 | 75 |
| | Emil Ruusuvuori | 6 | 73 | | Taro Daniel (WC) | 3 | 6 |
|
| Emil Ruusuvuori | 6 | 6 | | Nuno Borges (Q) | 1 | 4 |
|
| Taro Daniel (WC) | 4 | | | Arthur Rinderknech | 1 | Ret. |
| | Taro Daniel (WC) | 6 | 6 | | Alexander Zverev (13) | 0 | 4 |
|
| (BYE) | | Alexander Zverev (13) |
|
| | Jannik Sinner (10) | 6 | 6 | | Laslo Djere | 4 | 2 |
| | Jannik Sinner (10) | 6 | 6 | | Grigor Dimitrov (21) | 3 | 4 |
| | Jannik Sinner (10) | 6 | 6 | | Andrey Rublev (6) | 2 | 4 |
|
| Aleksandar Vukic (Q) | 2 | 6 | | Laslo Djere | 6 | 73 |
|
| Fabio Fognini | 4 | 7 | 4 | | Jan Lennard Struff (Q) | 6 | 5 | 6 |
| | Jan Lennard Struff (Q) | 6 | 6 | 4 | | Grigor Dimitrov (21) | 4 | 75 | 6 |
|
| (BYE) | | Grigor Dimitrov (21) |
|
| Miomir Kecmanović (29) | | (BYE) |
| | Miomir Kecmanović (29) | 6 | 6 | 73 | | Ugo Humbert | 4 | 75 | 6 |
| | Miomir Kecmanović (29) | 1 | 2 | | Andrey Rublev (6) | 6 | 6 |
|
| Ugo Humbert | 3 | | | Gaël Monfils | 3 | Ret. |
|
| Alexander Bublik | 5 | 3 | | J.J. Wolf | 7 | 6 |
| | J.J. Wolf | 6 | 4 | | Andrey Rublev (6) | 73 | 6 |
|
|
| | Hubert Hurkacz (8) | 6 | 77 | 76 | | Thanasi Kokkinakis (LL) | 710 | 6 | 6 |
| | Hubert Hurkacz (8) | 6 | 6 | | Adrian Mannarino | 75 | 70 |
| | Adrian Mannarino | 6 | 6 | | Christopher Eubanks (Q) | 72 | 75 |
| | Christopher Eubanks (Q) | 3 | 5 | | Daniil Medvedev (4) | 6 | 7 |
| | Daniil Medvedev (4) | | Karen Khachanov (14) |
|
| Thanasi Kokkinakis (LL) | 4 | 6 | 77 | | Zizou Bergs (WC) | 6 | 3 | 6 |
|
| Adrian Mannarino | 1 | 6 | 6 | | Juncheng Shang | 6 | 4 | 2 |
| | Adrian Mannarino | 6 | 3 | 6 | | Ben Shelton (32) | 4 | 6 | 1 |
|
|
| | Borna Ćorić (17) | 6 | 4 | 2 | | Christopher Eubanks (Q) | 3 | 6 | 6 |
| | Christopher Eubanks (Q) | 6 | 77 | 0 | | Grégoire Barrère | 3 | 6 | 0 |
|
| Christopher Eubanks (Q) | 72 | 6 | | Denis Kudla | 6 | 2 |
|
| Grégoire Barrère | 6 | 3 | 6 | | Roman Safiullin (Q) | 4 | 6 | 3 |
| | Grégoire Barrère | 6 | 6 | | Cameron Norrie (11) | 3 | 2 |
|
|
| | Alex de Minaur (15) | 75 | 6 | 6 | | Quentin Halys | 6 | 73 | 78 |
| | Quentin Halys | 72 | 6 | | Mackenzie McDonald | 6 | 3 |
| | Quentin Halys | 4 | 2 | | Daniil Medvedev (4) | 6 | 6 |
|
| Pedro Martínez | 2 | 6 | | Quentin Halys | 6 | 74 |
|
| Daniel Elahi Galán | 4 | 2 | | Mackenzie McDonald | 6 | 6 |
| | Mackenzie McDonald | 78 | 75 | | Matteo Berrettini (19) | 6 | 6 |
|
| (BYE) | | Matteo Berrettini (19) |
|
| Yoshihito Nishioka (28) | | (BYE) |
| | Yoshihito Nishioka (28) | 6 | 6 | 2 | | Alex Molčan | 75 | 1 | 6 |
| | Alex Molčan | | | Daniil Medvedev (4) | w.o. |
|
| Alex Molčan | 6 | 4 | 6 | | Jordan Thompson (Q) | 2 | 6 | 3 |
|
| Roberto Carballés Baena | 6 | 3 | | | Bernabé Zapata Miralles | 0 | 0 | Ret. |
| | Roberto Carballés Baena | 1 | 2 | | Daniil Medvedev (4) | 6 | 6 |
|
|
| Félix Auger-Aliassime (5) | | (BYE) |
| | Félix Auger-Aliassime (5) | 75 | 78 | | Thiago Monteiro | 6 | 6 |
| | Félix Auger-Aliassime (5) | 2 | 5 | | Francisco Cerúndolo (25) | 6 | 7 |
| | Francisco Cerúndolo (25) | 3 | 6 | 6 | | Lorenzo Sonego | 6 | 3 | 2 |
| | Francisco Cerúndolo (25) | 3 | 2 | | Karen Khachanov (14) | 6 | 6 |
|
| Thiago Monteiro | 6 | 76 | | Jason Kubler | 4 | 6 |
|
| Aleksandar Kovačević (LL) | 74 | 2 | 6 | | Jaume Munar | 6 | 6 | 1 |
| | Aleksandar Kovačević (LL) | 4 | 4 | | Francisco Cerúndolo (25) | 6 | 6 |
|
| (BYE) | | Francisco Cerúndolo (25) |
|
| | Daniel Evans (23) | 6 | 3 | 2 | | Lorenzo Sonego | 4 | 6 | 6 |
| | Lorenzo Sonego | 6 | 6 | | Frances Tiafoe (12) | 3 | 4 |
|
| Lorenzo Sonego | 77 | 6 | | Dominic Thiem (WC) | 6 | 2 |
|
| Yosuke Watanuki (Q) | 6 | 7 | | Benoît Paire (Q) | 4 | 5 |
| | Yosuke Watanuki (Q) | 75 | 6 | 4 | | Frances Tiafoe (12) | 6 | 73 | 6 |
|
|
| Karen Khachanov (14) | | (BYE) |
| | Karen Khachanov (14) | 6 | 3 | 6 | | Tomás Martín Etcheverry | 1 | 6 | 3 |
| | Karen Khachanov (14) | 6 | 6 | | Jiří Lehečka | 2 | 4 |
| | Karen Khachanov (14) | 74 | 6 | | Stefanos Tsitsipas (2) | 6 | 4 |
|
| Pavel Kotov (Q) | 2 | 2 | | Tomás Martín Etcheverry | 6 | 6 |
|
| Federico Coria | 3 | 4 | | Jiří Lehečka | 6 | 6 |
| | Jiří Lehečka | 6 | 6 | | Lorenzo Musetti (18) | 4 | 4 |
|
| (BYE) | | Lorenzo Musetti (18) |
|
| | Sebastián Báez (27) | 6 | 3 | | Cristian Garín (Q) | 72 | 6 |
| | Cristian Garín (Q) | 3 | 6 | 4 | | Stefanos Tsitsipas (2) | 6 | 4 | 6 |
|
| Marcos Giron | 4 | 6 | 4 | | Cristian Garín (Q) | 6 | 2 | 6 |
|
| Richard Gasquet | 6 | 3 | 6 | | Christopher O'Connell (LL) | 4 | 6 | 1 |
| | Richard Gasquet | | | Stefanos Tsitsipas (2) | w.o. |
|
| (BYE) | | Stefanos Tsitsipas (2) |
|
|
