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| Novak Djoković (1) | 6 | 75 | | Taylor Fritz | 3 | 6 |
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| Novak Djoković (1) | 6 | 6 | | Alejandro Davidovich Fokina (Q) | 2 | 1 |
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| Novak Djoković (1) | 4 | 7 | 7 | | Stefanos Tsitsipas (5) | 6 | 5 | 5 |
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| Novak Djoković (1) | 6 | 6 | 6 | | Lorenzo Sonego | 3 | 75 | 2 |
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| Novak Djoković (1) | 5 | 6 | 3 | | Rafael Nadal (2) | 7 | 1 | 6 |
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| Daniel Evans | 3 | 2 | | Taylor Fritz | 6 | 6 |
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| Roberto Carballés Baena (Q) | 4 | 4 | | Cameron Norrie (Q) | 6 | 6 |
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| Cameron Norrie (Q) | 2 | 3 | | Alejandro Davidovich Fokina (Q) | 6 | 6 |
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| Alejandro Davidovich Fokina (Q) | 6 | 72 | | Grigor Dimitrov (16) | 4 | 6 |
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| Matteo Berrettini (9) | 4 | 6 | 6 | | Nikoloz Basilashvili | 6 | 2 | 4 |
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| Matteo Berrettini (9) | 6 | 6 | | John Millman | 4 | 2 |
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| Matteo Berrettini (9) | 6 | 2 | | Stefanos Tsitsipas (5) | 73 | 6 |
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| John Millman | 6 | 6 | | Dušan Lajović | 3 | 4 |
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| Marin Čilić | 4 | 6 | 6 | | Alexander Bublik | 6 | 2 | 3 |
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| Marin Čilić | 5 | 2 | | Stefanos Tsitsipas (5) | 7 | 6 |
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| (BYE) | | Stefanos Tsitsipas (5) |
|
|
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| Dominic Thiem (4) | 3 | 75 | 6 | | Márton Fucsovics | 6 | 6 | 0 |
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| Dominic Thiem (4) | 4 | 75 | 6 | | Lorenzo Sonego | 6 | 6 | 75 |
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| Lorenzo Sonego | 3 | 6 | 6 | | Andrey Rublev (7) | 6 | 4 | 3 |
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| Yoshihito Nishioka (LL) | 0 | 2 | | Márton Fucsovics | 6 | 6 |
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| Gianluca Mager (WC) | 6 | 6 | | Alex de Minaur | 4 | 3 |
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| Gianluca Mager (WC) | 4 | 4 | | Lorenzo Sonego | 6 | 6 |
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| Lorenzo Sonego | 6 | 5 | 6 | | Gaël Monfils (14) | 4 | 7 | 4 |
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| Roberto Bautista Agut (10) | 6 | 6 | | Tommy Paul (Q) | 3 | 4 |
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| Roberto Bautista Agut (10) | 75 | 6 | | Cristian Garín | 6 | 3 |
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| Roberto Bautista Agut (10) | 4 | 4 | | Andrey Rublev (7) | 6 | 6 |
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| Lloyd Harris | 5 | 2 | | Cristian Garín | 7 | 6 |
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| Aljaž Bedene (LL) | 3 | 1 | | Jan Lennard Struff | 6 | 6 |
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| Jan Lennard Struff | 77 | 1 | 4 | | Andrey Rublev (7) | 6 | 6 | 6 |
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|
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| Diego Schwartzman (8) | | (BYE) |
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| Diego Schwartzman (8) | 1 | 3 | | Félix Auger-Aliassime | 6 | 6 |
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| Félix Auger-Aliassime | 6 | 1 | | Federico Delbonis (Q) | 73 | 6 |
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| Federico Delbonis (Q) | 5 | 6 | | Reilly Opelka | 7 | 72 |
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| Reilly Opelka | 4 | 4 | | Rafael Nadal (2) | 6 | 6 |
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| Filip Krajinović | 3 | 75 | 4 | | Félix Auger-Aliassime | 6 | 6 | 6 |
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| Karen Khachanov | 6 | 4 | 0 | | Federico Delbonis (Q) | 3 | 6 | 6 |
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| Federico Delbonis (Q) | 6 | 6 | | David Goffin (12) | 2 | 1 |
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| Salvatore Caruso (WC) | 4 | 1 | | David Goffin (12) | 6 | 6 |
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| Hubert Hurkacz (15) | 4 | 0 | Ret. | | Lorenzo Musetti (WC) | 6 | 2 | |
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| Lorenzo Musetti (WC) | 4 | 4 | | Reilly Opelka | 6 | 6 |
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| Reilly Opelka | 76 | 6 | | Aslan Karatsev | 6 | 4 |
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| Richard Gasquet | 1 | 5 | | Reilly Opelka | 6 | 7 |
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| Miomir Kecmanović | 6 | 4 | | Aslan Karatsev | 72 | 6 |
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| Aslan Karatsev | 6 | 6 | | Daniil Medvedev (3) | 2 | 4 |
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|
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| Alexander Zverev (6) | | (BYE) |
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| Alexander Zverev (6) | 6 | 6 | | Hugo Dellien (Q) | 2 | 2 |
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| Alexander Zverev (6) | 4 | 6 | 6 | | Kei Nishikori | 6 | 3 | 4 |
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| Alexander Zverev (6) | 3 | 4 | | Rafael Nadal (2) | 6 | 6 |
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| Hugo Dellien (Q) | 2 | 7 | 6 | | Adrian Mannarino | 6 | 5 | 2 |
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| Kei Nishikori | 6 | 6 | | Fabio Fognini | 3 | 4 |
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| Kei Nishikori | w.o. | | Pablo Carreño Busta (11) | |
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| Laslo Djere | 6 | 3 | 1 | | Pablo Carreño Busta (11) | 4 | 6 | 6 |
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| Denis Shapovalov (13) | 6 | 6 | | Kamil Majchrzak (Q) | 1 | 3 |
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| Denis Shapovalov (13) | 72 | 6 | | Stefano Travaglia (WC) | 6 | 3 |
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| Denis Shapovalov (13) | 6 | 4 | 6 | | Rafael Nadal (2) | 3 | 6 | 73 |
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| Stefano Travaglia (WC) | 6 | 6 | | Benoît Paire | 4 | 3 |
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| Ugo Humbert | 2 | 4 | | Jannik Sinner | 6 | 6 |
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| Jannik Sinner | 5 | 4 | | Rafael Nadal (2) | 7 | 6 |
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