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| Rafael Nadal (1) | 3 | 6 | 6 | | Ilya Ivashka (Q) | 6 | 2 | 4 |
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| Rafael Nadal (1) | 6 | 2 | 6 | | Kei Nishikori | 0 | 6 | 2 |
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| Rafael Nadal (1) | 6 | 6 | | Cameron Norrie | 1 | 4 |
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| Ilya Ivashka (Q) | 6 | 6 | | Tallon Griekspoor (Q) | 3 | 1 |
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| Kei Nishikori | 4 | 74 | 6 | | Guido Pella | 6 | 6 | 2 |
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| Kei Nishikori | 75 | 4 | 6 | | Cristian Garín (13) | 6 | 6 | 1 |
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| Karen Khachanov (12) | | (BYE) |
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| Karen Khachanov (12) | 4 | 6 | 3 | | Cameron Norrie | 6 | 3 | 6 |
|
| Cameron Norrie | 6 | 3 | | | David Goffin (8) | 0 | 5 | Ret. |
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| Cameron Norrie | 6 | 6 | | Salvatore Caruso | 1 | 2 |
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| Sumit Nagal (Q) | 5 | 0 | | Pierre Hugues Herbert | 7 | 6 |
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| Pierre Hugues Herbert | 2 | 4 | | David Goffin (8) | 6 | 6 |
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| Diego Schwartzman (4) | | (BYE) |
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| Diego Schwartzman (4) | 3 | 7 | 6 | | Frances Tiafoe | 6 | 5 | 1 |
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| Diego Schwartzman (4) | 6 | 6 | | Corentin Moutet | 4 | 2 |
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| Diego Schwartzman (4) | | Pablo Carreño Busta (6) |
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| Carlos Alcaraz (WC) | 4 | 6 | | Frances Tiafoe | 6 | 72 |
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| Dominik Köpfer | 5 | 2 | | Corentin Moutet | 7 | 6 |
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| Corentin Moutet | 6 | 5 | 6 | | Daniel Evans (16) | 4 | 7 | 3 |
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| Fabio Fognini (9) | 0 | 4 | Dsq. | | Bernabe Zapata Miralles (Q) | 6 | 4 | |
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| Bernabe Zapata Miralles (Q) | 3 | 4 | | Pablo Carreño Busta (6) | 6 | 6 |
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| Bernabe Zapata Miralles (Q) | 6 | 7 | 6 | | Andrey Kuznetsov (Q) | 74 | 5 | 1 |
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| Jordan Thompson | 75 | 4 | 73 | | Richard Gasquet | 6 | 6 | 6 |
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| Jordan Thompson | 4 | 0 | | Pablo Carreño Busta (6) | 6 | 6 |
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| (BYE) | | Pablo Carreño Busta (6) |
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| Roberto Bautista Agut (5) | | (BYE) |
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| Roberto Bautista Agut (5) | 6 | 6 | | Pablo Andújar | 4 | 0 |
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| Roberto Bautista Agut (5) | 6 | 2 | | Jannik Sinner (11) | 79 | 6 |
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| Jannik Sinner (11) | 6 | 76 | | Andrey Rublev (3) | 2 | 6 |
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| Jannik Sinner (11) | | Stefanos Tsitsipas (2) |
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| Gilles Simon | 1 | 6 | 3 | | Pablo Andújar | 6 | 3 | 6 |
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| Jo-Wilfried Tsonga | 5 | 1 | | Egor Gerasimov | 7 | 6 |
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| Egor Gerasimov | 3 | 2 | | Jannik Sinner (11) | 6 | 6 |
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| Adrian Mannarino | 4 | 4 | | Albert Ramos Viñolas | 6 | 6 |
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| Albert Ramos Viñolas | 4 | 74 | 4 | | Andrey Rublev (3) | 6 | 6 | 6 |
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| Albert Ramos Viñolas | 6 | 6 | 72 | | Holger Vitus Nødskov Rune (Q) | 72 | 1 | 6 |
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| Benoît Paire | 5 | 3 | | Federico Gaio (LL) | 7 | 6 |
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| Federico Gaio (LL) | 4 | 3 | | Andrey Rublev (3) | 6 | 6 |
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| Denis Shapovalov (7) | | (BYE) |
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| Denis Shapovalov (7) | 6 | 7 | | Jérémy Chardy | 3 | 5 |
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| Denis Shapovalov (7) | 2 | 3 | | Félix Auger-Aliassime (10) | 6 | 6 |
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| Félix Auger-Aliassime (10) | 3 | 3 | | Stefanos Tsitsipas (2) | 6 | 6 |
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| Jérémy Chardy | 6 | 3 | 6 | | Nikoloz Basilashvili | 4 | 6 | 3 |
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| Feliciano López | 4 | 3 | | Lorenzo Musetti (WC) | 6 | 6 |
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| Lorenzo Musetti (WC) | 6 | 3 | 0 | | Félix Auger-Aliassime (10) | 4 | 6 | 6 |
|
| (BYE) | | Félix Auger-Aliassime (10) |
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| Alex de Minaur (14) | 73 | 6 | | Alexander Bublik | 6 | 2 |
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| Alex de Minaur (14) | 5 | 3 | | Stefanos Tsitsipas (2) | 7 | 6 |
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| Alejandro Davidovich Fokina | 6 | 5 | 2 | | Alexander Bublik | 2 | 7 | 6 |
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| Thiago Monteiro | 3 | 5 | | Jaume Munar (WC) | 6 | 7 |
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| Jaume Munar (WC) | 0 | 2 | | Stefanos Tsitsipas (2) | 6 | 6 |
|
| (BYE) | | Stefanos Tsitsipas (2) |
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