| Alexander Zverev (1) | | (BYE) |
| | Alexander Zverev (1) | 6 | 6 | 6 | | Tallon Griekspoor | 4 | 75 | 74 |
| | Tallon Griekspoor | 73 | 6 | | Giovanni Mpetshi Perricard (29) | 6 | 3 |
| | Tallon Griekspoor | 74 | 6 | | Yosuke Watanuki (Q) | 6 | 1 |
| | Tallon Griekspoor | 7 | 0 | 3 | | Holger Rune (12) | 5 | 6 | 6 |
| | Holger Rune (12) | 7 | 6 | | Daniil Medvedev (5) | 5 | 4 |
| | Holger Rune (12) | | Jack Draper (13) |
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| Miomir Kecmanović | 75 | 4 | 3 | | Tallon Griekspoor | 6 | 6 | 6 |
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| Fábián Marozsán | 6 | 6 | | Pedro Martínez | 3 | 2 |
| | Fábián Marozsán | 4 | Ab. | | Giovanni Mpetshi Perricard (29) | 6 | |
|
| (BYE) | | Giovanni Mpetshi Perricard (29) |
|
| | Tomáš Macháč (19) | 6 | 2 | Ab. | | Yosuke Watanuki (Q) | 4 | 4 | |
| | Yosuke Watanuki (Q) | 6 | 76 | | Frances Tiafoe (16) | 4 | 6 |
|
| Alexander Bublik | 3 | 6 | 3 | | Yosuke Watanuki (Q) | 6 | 3 | 6 |
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| Roberto Bautista Agut | 4 | 6 | 6 | | Damir Džumhur (Q) | 6 | 1 | 74 |
| | Damir Džumhur (Q) | 6 | 6 | | Frances Tiafoe (16) | 74 | 77 |
|
|
| | Holger Rune (12) | 6 | 6 | | Corentin Moutet | 2 | 4 |
| | Holger Rune (12) | 5 | 6 | 7 | | Ugo Humbert (18) | 7 | 4 | 5 |
| | Holger Rune (12) | 6 | 6 | | Stefanos Tsitsipas (8) | 4 | 4 |
|
| Corentin Moutet | 6 | 4 | 6 | | Jordan Thompson | 4 | 6 | 3 |
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| Jaume Munar | 2 | 7 | 6 | | Kei Nishikori | 6 | 5 | 73 |
| | Kei Nishikori | 4 | 3 | | Ugo Humbert (18) | 6 | 6 |
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| Matteo Berrettini (28) | | (BYE) |
| | Matteo Berrettini (28) | 6 | 72 | | Christopher O'Connell | 2 | 6 |
| | Matteo Berrettini (28) | 3 | 3 | | Stefanos Tsitsipas (8) | 6 | 6 |
|
| Roberto Carballés Baena | 3 | 6 | 1 | | Christopher O'Connell | 6 | 0 | 6 |
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| Thiago Seyboth Wild | 4 | 7 | 76 | | Alexandre Müller | 6 | 5 | 6 |
| | Thiago Seyboth Wild | 2 | 4 | | Stefanos Tsitsipas (8) | 6 | 6 |
|
| (BYE) | | Stefanos Tsitsipas (8) |
|
| | Casper Ruud (4) | 6 | 6 | 2 | | Marcos Giron | 74 | 3 | 6 |
| | Marcos Giron | 5 | 6 | 6 | | Alexei Popyrin (26) | 7 | 3 | 3 |
| | Marcos Giron | 2 | 6 | 3 | | Arthur Fils (20) | 6 | 2 | 6 |
| | Arthur Fils (20) | 4 | 6 | 6 | | Daniil Medvedev (5) | 6 | 2 | 77 |
|
| Marcos Giron | 7 | 73 | | Nikoloz Basilashvili (Q) | 5 | 6 |
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| Zizou Bergs | 72 | 6 | | Ethan Quinn (Q) | 6 | 3 |
| | Zizou Bergs | 6 | 5 | | Alexei Popyrin (26) | 74 | 7 |
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|
| | Arthur Fils (20) | 6 | 6 | | Gabriel Diallo (LL) | 2 | 2 |
| | Arthur Fils (20) | 3 | 74 | 6 | | Lorenzo Musetti (15) | 6 | 6 | 3 |
|
| Zhizhen Zhang | 6 | 2 | 6 | | Gabriel Diallo (LL) | 2 | 6 | 77 |
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| Roman Safiullin | 7 | 6 | | Reilly Opelka (WC) | 5 | 4 |
| | Roman Safiullin | 5 | 7 | 2 | | Lorenzo Musetti (15) | 7 | 5 | 6 |
|
| (BYE) | | Lorenzo Musetti (15) |
|
| | Tommy Paul (10) | 6 | 6 | | Tristan Boyer (WC) | 3 | 1 |
| | Tommy Paul (10) | 6 | 7 | | Cameron Norrie | 3 | 5 |
| | Tommy Paul (10) | 4 | 0 | | Daniil Medvedev (5) | 6 | 6 |
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| Tristan Boyer (WC) | 4 | 6 | 74 | | Aleksandar Vukic | 6 | 2 | 6 |
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| Cameron Norrie | 6 | 6 | | Luca Nardi | 0 | 3 |
| | Cameron Norrie | 3 | 6 | 7 | | Jiří Lehečka (23) | 6 | 4 | 5 |
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| | Alex Michelsen (31) | 6 | 6 | | Colton Smith (Q) | 3 | 4 |
| | Alex Michelsen (31) | 0 | Ab. | | Daniil Medvedev (5) | 2 | |
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| Colton Smith (Q) | 3 | 6 | 6 | | Flavio Cobolli | 6 | 2 | 2 |
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| Yunchaokete Bu | 7 | 6 | | Nishesh Basavareddy (WC) | 5 | 4 |
| | Yunchaokete Bu | 2 | 2 | | Daniil Medvedev (5) | 6 | 6 |
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|
| | Andrey Rublev (7) | 4 | 5 | | Matteo Arnaldi | 6 | 7 |
| | Matteo Arnaldi | 2 | 4 | | Brandon Nakashima (32) | 6 | 6 |
| | Brandon Nakashima (32) | 6 | 1 | | Ben Shelton (11) | 76 | 6 |
| | Ben Shelton (11) | 4 | 5 | | Jack Draper (13) | 6 | 7 |
| | Jack Draper (13) | 6 | 0 | 6 | | Carlos Alcaraz (2) | 1 | 6 | 4 |
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| Matteo Arnaldi | 6 | 5 | 6 | | Aleksandar Kovačević | 3 | 7 | 4 |
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| Alexander Shevchenko | 1 | 3 | | Rinky Hijikata | 6 | 6 |
| | Rinky Hijikata | 5 | 1 | | Brandon Nakashima (32) | 7 | 6 |
|
| (BYE) | | Brandon Nakashima (32) |
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| Karen Khachanov (22) | | (BYE) |
| | Karen Khachanov (22) | 3 | 6 | 6 | | Jakub Menšík | 6 | 0 | 3 |
| | Karen Khachanov (22) | 3 | 5 | | Ben Shelton (11) | 6 | 7 |
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| Tomás Martín Etcheverry | 4 | 6 | | Jakub Menšík | 6 | 76 |
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| Mariano Navone | 7 | 6 | | Learner Tien | 5 | 4 |
| | Mariano Navone | 3 | 2 | | Ben Shelton (11) | 6 | 6 |
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|
| | Jack Draper (13) | 6 | 6 | | Joao Fonseca (WC) | 4 | 0 |
| | Jack Draper (13) | 7 | 6 | | Jenson Brooksby | 5 | 4 |
| | Jack Draper (13) | 7 | 6 | | Taylor Fritz (3) | 5 | 4 |
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| Jacob Fearnley | 2 | 6 | 3 | | Joao Fonseca (WC) | 6 | 1 | 6 |
|
| Benjamin Bonzi | 6 | 5 | 5 | | Jenson Brooksby | 1 | 7 | 7 |
| | Jenson Brooksby | 6 | 6 | | Félix Auger-Aliassime (17) | 4 | 2 |
|
| (BYE) | | Félix Auger-Aliassime (17) |
|
| Alejandro Tabilo (30) | | (BYE) |
| | Alejandro Tabilo (30) | 6 | 7 | | Dušan Lajović | 3 | 5 |
| | Alejandro Tabilo (30) | 6 | 3 | 1 | | Taylor Fritz (3) | 4 | 6 | 6 |
|
| Li Tu (Q) | 2 | 0 | | Dušan Lajović | 6 | 6 |
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| Matteo Gigante (Q) | 3 | 6 | 6 | | Sebastián Báez | 6 | 1 | 4 |
| | Matteo Gigante (Q) | 3 | 5 | | Taylor Fritz (3) | 6 | 7 |
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|
| | Novak Djoković (6) | 2 | 6 | 1 | | Botic van de Zandschulp (LL) | 6 | 3 | 6 |
| | Botic van de Zandschulp (LL) | 3 | 4 | | Francisco Cerúndolo (25) | 6 | 6 |
| | Francisco Cerúndolo (25) | 7 | 6 | | Alex de Minaur (9) | 5 | 3 |
| | Francisco Cerúndolo (25) | 3 | 6 | | Carlos Alcaraz (2) | 6 | 74 |
|
| Botic van de Zandschulp (LL) | 77 | 3 | | | Nick Kyrgios | 6 | 0 | Ab. |
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| Mackenzie McDonald (WC) | 2 | 6 | 6 | | Alejandro Davidovich Fokina | 6 | 3 | 2 |
| | Mackenzie McDonald (WC) | 6 | 6 | 1 | | Francisco Cerúndolo (25) | 4 | 73 | 6 |
|
| (BYE) | | Francisco Cerúndolo (25) |
|
| | Hubert Hurkacz (21) | 7 | 6 | | Hugo Gaston (Q) | 5 | 3 |
| | Hubert Hurkacz (21) | 4 | 0 | | Alex de Minaur (9) | 6 | 6 |
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| Luciano Darderi | 3 | 3 | | Hugo Gaston (Q) | 6 | 6 |
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| David Goffin | 6 | 7 | | Lorenzo Sonego | 4 | 5 |
| | David Goffin | 2 | 2 | | Alex de Minaur (9) | 6 | 6 |
|
|
| Grigor Dimitrov (14) | | (BYE) |
| | Grigor Dimitrov (14) | 6 | 6 | | Nuno Borges | 3 | 4 |
| | Grigor Dimitrov (14) | 74 | 4 | 72 | | Gaël Monfils | 6 | 6 | 6 |
| | Grigor Dimitrov (14) | 1 | 1 | | Carlos Alcaraz (2) | 6 | 6 |
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| Arthur Rinderknech | 1 | 7 | 2 | | Nuno Borges | 6 | 5 | 6 |
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| Jan Lennard Struff | 4 | 4 | | Gaël Monfils | 6 | 6 |
| | Gaël Monfils | 72 | 74 | | Sebastian Korda (24) | 6 | 6 |
|
| (BYE) | | Sebastian Korda (24) |
|
| Denis Shapovalov (27) | | (BYE) |
| | Denis Shapovalov (27) | 6 | 6 | | Adam Walton (Q) | 3 | 2 |
| | Denis Shapovalov (27) | 2 | 4 | | Carlos Alcaraz (2) | 6 | 6 |
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| Giulio Zeppieri (Q) | 5 | 1 | | Adam Walton (Q) | 7 | 6 |
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| Quentin Halys | 6 | 6 | | Pablo Carreño Busta (Q) | 3 | 4 |
| | Quentin Halys | 4 | 2 | | Carlos Alcaraz (2) | 6 | 6 |
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