| | Jannik Sinner (1) | | Taro Daniel |
| | | | Tomás Martín Etcheverry (31) |
| | | | |
| Egor Gerasimov (Q) | 75 | 3 | 4 | | Taro Daniel | 6 | 6 | 6 |
|
| Pablo Carreño Busta | 6 | 2 | | Botic van de Zandschulp | 75 | 6 |
| | Botic van de Zandschulp | 6 | 6 | 5 | | Tomás Martín Etcheverry (31) | 75 | 3 | 7 |
|
| (BYE) | | Tomás Martín Etcheverry (31) |
|
| | Arthur Fils (21) | 6 | 6 | | Roberto Carballés Baena | 74 | 75 |
| | Roberto Carballés Baena | | Ben Shelton (16) |
|
| Roberto Bautista Agut | 6 | 3 | 2 | | Roberto Carballés Baena | 3 | 6 | 6 |
|
| Lorenzo Sonego | 6 | 6 | | Denis Shapovalov (Q) | 75 | 78 |
| | Denis Shapovalov (Q) | 3 | 5 | | Ben Shelton (16) | 6 | 7 |
|
|
| Stefanos Tsitsipas (10) | | (BYE) |
| | Stefanos Tsitsipas (10) | 76 | 6 | | Kei Nishikori (WC) | 6 | 4 |
| | Stefanos Tsitsipas (10) | | Alexandre Müller |
| |
| Kei Nishikori (WC) | 3 | 6 | 6 | | Mariano Navone | 6 | 4 | 3 |
|
| Luca Nardi | 6 | 1 | 1 | | Alexandre Müller | 4 | 6 | 6 |
| | Alexandre Müller | 6 | 6 | | Félix Auger-Aliassime (18) | 3 | 2 |
|
| (BYE) | | Félix Auger-Aliassime (18) |
|
| | Matteo Arnaldi (29) | 6 | 6 | 6 | | Zachary Svajda (Q) | 72 | 2 | 4 |
| | Matteo Arnaldi (29) | | Daniil Medvedev (5) |
|
| Adrian Mannarino | 3 | 6 | 0 | | Zachary Svajda (Q) | 6 | 1 | 6 |
|
| Thiago Seyboth Wild | 6 | 4 | 73 | | Daniel Evans (Q) | 2 | 6 | 6 |
| | Thiago Seyboth Wild | 5 | 5 | | Daniil Medvedev (5) | 7 | 7 |
|
|
| | Carlos Alcaraz (3) | | Juncheng Shang |
| | | |
| Juncheng Shang | 6 | 6 | | Coleman Wong (WC) | 4 | 4 |
|
| Yibing Wu (WC) | 6 | 6 | | Sumit Nagal | 3 | 3 |
| | Yibing Wu (WC) | 6 | 6 | | Nicolás Jarry (25) | 2 | 1 |
|
|
| | Sebastián Báez (22) | 3 | 6 | 4 | | Gaël Monfils | 6 | 4 | 6 |
| | Gaël Monfils | | Ugo Humbert (16) |
|
| Gaël Monfils | 6 | 6 | | Damir Džumhur | 4 | 3 |
|
| Marin Čilić | 4 | 4 | | Arthur Cazaux | 6 | 6 |
| | Arthur Cazaux | 3 | 2 | | Ugo Humbert (16) | 6 | 6 |
|
|
| | Tommy Paul (11) | 6 | 6 | | Fabio Fognini | 1 | 3 |
| | Tommy Paul (11) | | Alejandro Tabilo (19) |
| |
| Fabio Fognini | 6 | 6 | 6 | | Luciano Darderi | 4 | 75 | 4 |
|
| Reilly Opelka | 4 | 6 | | Arthur Rinderknech | 6 | 75 |
| | Arthur Rinderknech | 3 | 2 | | Alejandro Tabilo (19) | 6 | 6 |
|
| (BYE) | | Alejandro Tabilo (19) |
|
| | Tomáš Macháč (30) | 1 | 73 | 6 | | Alejandro Davidovich Fokina | 6 | 6 | 4 |
| | Tomáš Macháč (30) | | Aleksandar Vukic (Q) |
|
| Alejandro Davidovich Fokina | 7 | 77 | | Gabriel Diallo (Q) | 5 | 6 |
|
| Aleksandar Vukic (Q) | 2 | 6 | 6 | | Corentin Moutet | 6 | 3 | 4 |
| | Aleksandar Vukic (Q) | 6 | 6 | | Casper Ruud (8) | 4 | 4 |
|
|
| | Andrey Rublev (6) | | Jakub Menšík |
| | | | |
| Jakub Menšík | 6 | 5 | 6 | | Pedro Martínez | 1 | 7 | 4 |
|
| Ramkumar Ramanathan (Q) | 1 | 6 | | Alexander Shevchenko | 6 | 73 |
| | Alexander Shevchenko | | Francisco Cerúndolo (27) |
|
| (BYE) | | Francisco Cerúndolo (27) |
|
| | Alexei Popyrin (20) | | Miomir Kecmanović |
| |
| Miomir Kecmanović | 6 | 6 | | Rinky Hijikata | 2 | 2 |
|
| Zhizhen Zhang | 4 | 3 | | Zizou Bergs | 6 | 6 |
| | Zizou Bergs | | Grigor Dimitrov (9) |
|
|
| | Frances Tiafoe (13) | | Yi Zhou (WC) |
| | |
| Yoshihito Nishioka | 4 | Ab. | | Yi Zhou (WC) | 2 | |
|
| Beibit Zhukayev (Q) | 6 | 4 | | Roman Safiullin | 70 | 6 |
| | Roman Safiullin | | Alexander Bublik (23) |
|
| (BYE) | | Alexander Bublik (23) |
|
| | Flavio Cobolli (28) | | Stan Wawrinka (WC) |
| |
| Stan Wawrinka (WC) | 72 | 76 | | Giovanni Mpetshi Perricard | 6 | 6 |
|
| Alex Michelsen | 6 | 6 | | Yunchaokete Bu | 3 | 4 |
| | Alex Michelsen | | Novak Djoković (4) |
|
|
| | Taylor Fritz (7) | | Terence Atmane (Q) |
| | | |
| Aleksandar Kovačević | 4 | 6 | | Terence Atmane (Q) | 6 | 74 |
|
| Pavel Kotov | 76 | 4 | 5 | | Yosuke Watanuki (Q) | 6 | 6 | 7 |
| | Yosuke Watanuki (Q) | | Brandon Nakashima (32) |
|
| (BYE) | | Brandon Nakashima (32) |
|
| | Jiří Lehečka (33) | | Jaume Munar |
| |
| Jaume Munar | 6 | 6 | | Hugo Gaston | 3 | 3 |
|
| Christopher O'Connell | 6 | 6 | | Matteo Berrettini | 79 | 76 |
| | Matteo Berrettini | | Holger Rune (12) |
|
|
| Lorenzo Musetti (15) | | (BYE) |
| | Lorenzo Musetti (15) | | David Goffin |
| | |
| David Goffin | 6 | 6 | | James Duckworth | 4 | 2 |
|
| Li Tu (Q) | 1 | 6 | | Marcos Giron | 6 | 74 |
| | Marcos Giron | | Karen Khachanov (24) |
|
| (BYE) | | Karen Khachanov (24) |
|
| Jordan Thompson (26) | | (BYE) |
| | Jordan Thompson (26) | | Tallon Griekspoor |
| |
| Tallon Griekspoor | 6 | 6 | 6 | | Facundo Díaz Acosta | 4 | 76 | 3 |
|
| Mattia Bellucci (Q) | 6 | 6 | | Billy Harris (LL) | 3 | 4 |
| | Mattia Bellucci (Q) | | Alexander Zverev |
|
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