| | Novak Djoković (1) | | Corentin Moutet (LL) |
| | | | | |
| Corentin Moutet (LL) | 3 | 71 | 6 | | Roman Safiullin | 6 | 6 | 2 |
|
| Jakub Menšík | 3 | 2 | | Yannick Hanfmann | 6 | 6 |
| | Yannick Hanfmann | | Alejandro Tabilo (29) |
|
| (BYE) | | Alejandro Tabilo (29) |
|
| Francisco Cerúndolo (20) | | (BYE) |
| | Francisco Cerúndolo (20) | | Matteo Gigante (WC) |
| |
| Matteo Gigante (WC) | 72 | 6 | | Giulio Zeppieri (WC) | 6 | 4 |
|
| Alexander Shevchenko | 6 | 6 | | Fábián Marozsán | 3 | 2 |
| | Alexander Shevchenko | | Karen Khachanov (16) |
|
| (BYE) | | Karen Khachanov (16) |
|
| | Ben Shelton (12) | | Pavel Kotov |
| | |
| Pavel Kotov | 6 | 6 | | Alex Michelsen | 1 | 1 |
|
| Zhizhen Zhang | 6 | 7 | | Daniel Elahi Galán | 2 | 5 |
| | Zhizhen Zhang | | Adrian Mannarino (19) |
|
| (BYE) | | Adrian Mannarino (19) |
|
| Jordan Thompson (32) | | (BYE) |
| | Jordan Thompson (32) | | Thiago Monteiro (Q) |
| |
| Thiago Monteiro (Q) | 6 | 7 | | Gaël Monfils | 2 | 5 |
|
| Miomir Kecmanović | 6 | 6 | | Brandon Nakashima (Q) | 4 | 4 |
| | Miomir Kecmanović | | Casper Ruud (5) |
|
|
| Alexander Zverev (3) | | (BYE) |
| | Alexander Zverev (3) | | Aleksandar Vukic |
| | | |
| Diego Schwartzman (Q) | 2 | 2 | | Aleksandar Vukic | 6 | 6 |
|
| Luciano Darderi | 6 | 6 | 74 | | Denis Shapovalov | 74 | 3 | 6 |
| | Luciano Darderi | | Mariano Navone (28) |
|
|
| Tallon Griekspoor (23) | | (BYE) |
| | Tallon Griekspoor (23) | | Francesco Passaro (Q) |
| |
| Arthur Rinderknech | 73 | 5 | 6 | | Francesco Passaro (Q) | 6 | 7 | 77 |
|
| Nuno Borges | 6 | 6 | 78 | | Pedro Martínez | 73 | 4 | 6 |
| | Nuno Borges | | Alexander Bublik (15) |
|
| (BYE) | | Alexander Bublik (15) |
|
| | | |
| Daniel Evans | | Fabio Fognini (WC) |
|
| Maximilian Marterer (Q) | 4 | 2 | | Flavio Cobolli | 6 | 6 |
| | Flavio Cobolli | | Sebastian Korda (24) |
|
| (BYE) | | Sebastian Korda (24) |
|
| Lorenzo Musetti (26) | | (BYE) |
| | Lorenzo Musetti (26) | | Terence Atmane (Q) |
| |
| Christopher Eubanks | 4 | 4 | | Terence Atmane (Q) | 6 | 6 |
|
| Yoshihito Nishioka | 6 | 2 | 74 | | Sebastian Ofner | 3 | 6 | 6 |
| | Yoshihito Nishioka | | Grigor Dimitrov (8) |
|
|
| Stefanos Tsitsipas (6) | | (BYE) |
| | | | | |
| Jan Lennard Struff | | Pedro Cachín |
|
| Rinky Hijikata | 4 | 5 | | Jaume Munar | 6 | 7 |
| | Jaume Munar | | Cameron Norrie (27) |
|
|
| Félix Auger-Aliassime (18) | | (BYE) |
| | Félix Auger-Aliassime (18) | | |
| |
| Nicolas Moreno De Alboran (Q) | | Botic van de Zandschulp (Q) |
|
| Roberto Carballés Baena | | Christopher O'Connell |
| |
|
| | Juncheng Shang (LL) | | Stefano Napolitano (WC) |
| | |
| Stefano Napolitano (WC) | 6 | 73 | | J.J. Wolf (LL) | 2 | 6 |
|
| Harold Mayot (LL) | 6 | 5 | 4 | | Matteo Arnaldi | 3 | 7 | 6 |
| | Matteo Arnaldi | | Nicolás Jarry (21) |
|
|
| | |
| Alexandre Müller (Q) | | Márton Fucsovics |
|
| Emil Ruusuvuori | | Marcos Giron |
| |
|
| | Hubert Hurkacz (7) | | Rafael Nadal |
| | | |
| Zizou Bergs (Q) | 6 | 3 | 4 | | Rafael Nadal | 4 | 6 | 6 |
|
| Thiago Seyboth Wild | 6 | 6 | | Grégoire Barrère (Q) | 4 | 2 |
| | Thiago Seyboth Wild | | Tomás Martín Etcheverry (25) |
|
| (BYE) | | Tomás Martín Etcheverry (25) |
|
| | |
| Dušan Lajović | | Lorenzo Sonego |
|
| Daniel Altmaier | | Luca Nardi |
| |
|
| | | |
| Mackenzie McDonald | | Aslan Karatsev |
|
| Dominik Koepfer | 6 | 6 | | Andrea Vavassori (WC) | 4 | 3 |
| | Dominik Koepfer | | Frances Tiafoe (22) |
|
|
| Alejandro Davidovich Fokina (30) | | (BYE) |
| | Alejandro Davidovich Fokina (30) | | Hamad Medjedović (Q) |
| |
| Alexei Popyrin | 3 | 2 | | Hamad Medjedović (Q) | 6 | 6 |
|
| Jack Draper | 7 | 6 | | Borna Ćorić | 5 | 1 |
| | Jack Draper | | Daniil Medvedev (2) |
|
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